Decomposition of synthetic polymers induced by hydrogen atoms.

Dynamic diversity of synthetic supramolecular polymers in water as revealed by hydrogen/deuterium exchange

Numerous self-assembling molecules have been synthesized aiming at mimicking both the structural and dynamic properties found in living systems. Here we show the application of hydrogen/deuterium exchange (HDX) mass spectrometry (MS) to unravel the nanoscale organization and the structural dynamics of synthetic supramolecular polymers in water. We select benzene-1,3,5-tricarboxamide (BTA) deriv...

developments in the production of hydrogen by thermochemical water decomposition

recent developments in hydrogen production by thermochemical water decomposition are reported,with an emphasis on hydrogen production from non-fossil energy sources such as nuclear and solar. numerousdevelopments have been made on sulphur-iodine, copper-chlorine and other thermochemicalcycles. efforts are described to lower the temperatures required in thermochemical cycles, so as to broadenthe...

(2+1) laser-induced fluorescence of spin-polarized hydrogen atoms.

We report the measurement of the spin polarization of hydrogen (SPH) atoms by (2+1) laser-induced fluorescence, produced via the photodissociation of thermal HBr molecules with circularly polarized 193 nm light. This scheme, which involves two-photon laser excitation at 205 nm and fluorescence at 656 nm, offers an experimentally simpler polarization-detection method than the previously reported...

Characterizing synthetic polymers by MALDI MS.

Different polymer formulations possess unique chemical, physical, and mechanical properties. Small variations in the structure of a given polymer formulation can significantly change its characteristics, resulting in new functions and applications. For example, polyvinyl alcohol is a water-soluble synthetic polymer made by alcoholysis of polyvinyl acetate. Its chemical and physical properties d...

CO x Free Hydrogen Production by Catalytic Decomposition of Methane Over Porous Ni/Al2O3 Catalysts